precipitation / age hardening
what is precipitation hardening?
Precipitation hardening, also known as aging (age hardening), is used to increase the yield strength of certain metals. The hardness of the metals is also increased. Precipitation hardening is often applied to maraging steel, some martensitic stainless steel types (PH steels, precipitation-hardenable stainless steel), or other metals such as aluminum, titanium, and copper alloys.
Parts to be treated are typically purchased in the solution-annealed condition and then machined (the metal is relatively soft at this stage). By varying the time at temperature and the temperature itself during precipitation hardening, different properties can be achieved.
precipitation hardening process
The exact heat treatment process determines the desired mechanical properties and hardness. It is important that the process is carried out accurately. An incorrect temperature or time leads to different properties.
1. solution annealing
The first step is solution annealing. This is necessary because the structure may not be homogeneous (microsegregation). It is important to remain at the solution temperature long enough. During this step, all (alloying) elements are brought into solution. By then cooling quickly enough, all elements remain in a solid solution state. The result is that the structure is returned to its original homogeneous state, making it optimal for subsequent precipitation hardening (aging).
The metal alloy is heated until all elements are in solution. The temperature must be high enough; otherwise, especially coarser elements will not dissolve sufficiently, and the required properties will not be achieved. On the other hand, the eutectic temperature of the alloy must not be exceeded, as this could cause areas with accumulations of alloying elements to melt.
2. cooling
Diffusion and thus the formation of unwanted precipitates can be prevented by rapid cooling (quenching). The solid state then remains in a metastable, supersaturated single-phase condition. This is achieved by cooling at least at the critical rate known for the alloy. Cold or heated water, oil, or sometimes gas can be used for rapid quenching.
Many nuclei (needed for later precipitation hardening) are formed during quenching.
3. precipitation hardening (age hardening)
Further precipitation hardening, typically somewhere between 150°C and 650°C (the temperature depends on the chosen alloy), accelerates diffusion, and the supersaturated single-phase solid solution is transformed into a two-phase alloy by the formation of precipitates (clusters).
- The phase that is coherent in volume and generally occurs with a higher proportion is called matrix.
- The newly formed phase is called precipitate.
The many small precipitates are homogeneously distributed in the microstructure. This makes it possible to specifically tailor the properties of the metal product.
The temperature determines the diffusion rate, the type of precipitate, and the rate of precipitation formation. Nucleation, the growth of the nuclei, and the final precipitation hardening can be controlled.
advantages of precipitation hardening
There are various advantages associated with the use of precipitation hardening. It is important to note that the benefits of precipitation hardening are highly dependent on the specific alloy and process parameters.
Here are some of the benefits:
- Effective prevention of dislocation movement
- Significant increase in strength and yield strength
- Increased resistance to plastic deformation
suitable materials
Materials that are suitable for precipitation hardening are often specially developed – such as maraging steels or PH steel (precipitation-hardenable stainless steel).
It is a process that is often used for aluminum, copper, nickel and some steel alloys.
Steels
| Alloy | Type | Precipitate | Solution annealing (°C) | Aging (°C) |
| Maraging steel | Ni-rich steel | Ni3Ti, Ni3Mo | 820–850 | 480–510 |
| NAK55 | Low-carbon steel |
Aluminium alloys
| Alloy | Serie | Matrix | Precipitate | Solution anneal (°C) | Aging (°C) |
| Al 2024 | 2xxx | Al–Cu | Al2Cu | 495–505 | 190–200 |
| Al 2019 | 2xxx | Al–Cu | Al2Cu | ~500 | 160–190 |
| Y-alloy | 2xxx | Al–Cu–Ni | Al2Cu, Al3Ni | 500–520 | 200–250 |
| Hiduminium | 2xxx | Al–Cu–Mg–Ni | Al2Cu, Mg2Si | 510–525 | 180–220 |
| Al 6061 | 6xxx | Al–Mg–Si | Mg2Si | 530–550 | 160–180 |
| Al 7075 | 7xxx | Al–Zn–Mg–Cu | MgZn2 | 470–480 | 120–160 |
| Al 7475 | 7xxx | Al–Zn–Mg–Cu | MgZn2 | 470–480 | 120–160 |
PH Stainless alloys
| Precipitation Hardened Stainless Steels | |||||||
| Name | Typical Composition, % | ||||||
| C | Cr | Ni | Cu | Mo | Al | Other | |
| Single Treatment (martensitic) Steels | |||||||
| Stainless “W” | 0.07 | 17 | 7.0 | 0.2 | Ti – 0.7 | ||
| 17-4 PH | 0.04 | 17 | 4.0 | 1.0 | Cb – 0.3 | ||
| 15-5 PH | 0.04 | 15 | 5.0 | 4.0 | Cb – 0.3 | ||
| PH 13-8 Mo | 0.04 | 13 | 8.0 | 2.0 | 1.0 | ||
| Double Treatment (Semi-Austenitic) Steels | |||||||
| 17-7 PH | 0.07 | 17 | 7.0 | 1.0 | |||
| PH 15-7 Mo | 0.07 | 15 | 7.0 | 2.0 | 1.0 | ||
| PH 14-8 Mo | 0.04 | 14 | 8.0 | 2.0 | 1.0 | ||
| AM 350 | 0.08 | 17 | 4.0 | 3.0 | |||
| Alloy 355 | 0.12 | 15.5 | 4.5 | N – 0.10 | |||
| Austenitic Precipitation Hardening Steels | |||||||
| 17-10 P | 0.12 | 17 | 10.0 | P – 0.25 | |||
| HNM Alloy | 0.03 | 19 | 9.0 | Mn – 3.5, P – 0.3 | |||
| A 286 | 0.05 | 15 | 25.0 | 1.5 | 0.15 | Ti – 2.2, V – 0.3 | |
Superalloys
| Alloy X-750 | Matrix | Precipitate | Solution annealing (°C) | Aging (°C) |
| Inconel 718 | Ni-basis | γ’ + γ” | 980–1050 | 720 + 620 |
| Alloy X-750 | Ni-basis | γ’ | 980–1050 | 700–760 |
| René 41 | Ni-basis | γ’ | 1050–1080 | 760–815 |
| Waspaloy | Ni-basis | γ’ | 1040–1065 | 760–850 |
Various
| Alloy | Matrix | Precipitate | Solution annealing (°C) | Aging (°C) |
| Ti-6Al-4V | Titanium | α β | 950–1000 | 480–600 |
| Cu-Be | Copper | Be-precipitates | 760–800 | 315–350 |
| Mulberry (U) | U-Mo | U-Mo precipitates | 800–900 | 350–500 |

precipitation hardening for various industries
Precipitation hardening is applied in almost all industries. Critical factors are the metal to be used and the required mechanical properties for the application.
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frequently asked questions about precipitation hardening
Which materials are suitable for precipitation hardening?
Precipitation hardening is the main method to increase the strength of certain copper, titanium, and aluminum alloys. These alloys do not have the possibility of a polymorphic phase transformation and therefore cannot be hardened classically (as is possible for martensite).
What is a yield strength?
The yield strength describes the limit of elastic strain before it transitions into permanent plastic strain (deformation). This is determined with a uniaxial and uniform tensile test. For many materials, the yield strength cannot be clearly determined with a tensile test or is not clear. Therefore, the 0.2% yield strength is often used instead.
How long does the precipitation hardening process take?
The temperature determines the diffusion rate, the type of precipitate, and the rate of precipitation formation. Nucleation, the growth of the nuclei, and the final precipitation hardening can be controlled.
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