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precipitation / age hardening

Aalberts surface technologies > processes > precipitation / age hardening
precipitation hardening
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what is precipitation hardening?

Precipitation hardening, also known as aging (age hardening), is used to increase the yield strength of certain metals. The hardness of the metals is also increased. Precipitation hardening is often applied to maraging steel, some martensitic stainless steel types (PH steels, precipitation-hardenable stainless steel), or other metals such as aluminum, titanium, and copper alloys.

Parts to be treated are typically purchased in the solution-annealed condition and then machined (the metal is relatively soft at this stage). By varying the time at temperature and the temperature itself during precipitation hardening, different properties can be achieved.

precipitation hardening process

The exact heat treatment process determines the desired mechanical properties and hardness. It is important that the process is carried out accurately. An incorrect temperature or time leads to different properties.

1. solution annealing

The first step is solution annealing. This is necessary because the structure may not be homogeneous (microsegregation). It is important to remain at the solution temperature long enough. During this step, all (alloying) elements are brought into solution. By then cooling quickly enough, all elements remain in a solid solution state. The result is that the structure is returned to its original homogeneous state, making it optimal for subsequent precipitation hardening (aging).

The metal alloy is heated until all elements are in solution. The temperature must be high enough; otherwise, especially coarser elements will not dissolve sufficiently, and the required properties will not be achieved. On the other hand, the eutectic temperature of the alloy must not be exceeded, as this could cause areas with accumulations of alloying elements to melt.

2. cooling

Diffusion and thus the formation of unwanted precipitates can be prevented by rapid cooling (quenching). The solid state then remains in a metastable, supersaturated single-phase condition. This is achieved by cooling at least at the critical rate known for the alloy. Cold or heated water, oil, or sometimes gas can be used for rapid quenching.

Many nuclei (needed for later precipitation hardening) are formed during quenching.

3. precipitation hardening (age hardening)

Further precipitation hardening, typically somewhere between 150°C and 650°C (the temperature depends on the chosen alloy), accelerates diffusion, and the supersaturated single-phase solid solution is transformed into a two-phase alloy by the formation of precipitates (clusters).

  • The phase that is coherent in volume and generally occurs with a higher proportion is called matrix.
  • The newly formed phase is called precipitate.

The many small precipitates are homogeneously distributed in the microstructure. This makes it possible to specifically tailor the properties of the metal product.

The temperature determines the diffusion rate, the type of precipitate, and the rate of precipitation formation. Nucleation, the growth of the nuclei, and the final precipitation hardening can be controlled.

advantages of precipitation hardening

There are various advantages associated with the use of precipitation hardening. It is important to note that the benefits of precipitation hardening are highly dependent on the specific alloy and process parameters.

Here are some of the benefits:

  • Effective prevention of dislocation movement
  • Significant increase in strength and yield strength
  • Increased resistance to plastic deformation

suitable materials

Materials that are suitable for precipitation hardening are often specially developed – such as maraging steels or PH steel (precipitation-hardenable stainless steel).

It is a process that is often used for aluminum, copper, nickel and some steel alloys.

Steels

AlloyTypePrecipitateSolution annealing (°C)Aging (°C)
Maraging steelNi-rich steelNi3Ti, Ni3Mo820–850480–510
NAK55Low-carbon steel   

Aluminium alloys

AlloySerieMatrixPrecipitateSolution anneal  (°C)Aging (°C)
Al 20242xxxAl–CuAl2Cu495–505190–200
Al 20192xxxAl–CuAl2Cu~500160–190
Y-alloy2xxxAl–Cu–NiAl2Cu, Al3Ni500–520200–250
Hiduminium2xxxAl–Cu–Mg–NiAl2Cu, Mg2Si510–525180–220
Al 60616xxxAl–Mg–SiMg2Si530–550160–180
Al 70757xxxAl–Zn–Mg–CuMgZn2470–480120–160
Al 74757xxxAl–Zn–Mg–CuMgZn2470–480120–160

PH Stainless alloys

Precipitation Hardened Stainless Steels 
NameTypical Composition, %
CCrNiCuMoAlOther
 Single Treatment (martensitic) Steels
Stainless “W”0.07177.0  0.2Ti – 0.7
17-4 PH0.04174.01.0  Cb – 0.3
15-5 PH0.04155.04.0  Cb – 0.3
PH 13-8 Mo0.04138.0 2.01.0 
 Double Treatment (Semi-Austenitic) Steels 
17-7 PH0.07177.0  1.0 
PH 15-7 Mo0.07157.0 2.01.0 
PH 14-8 Mo0.04148.0 2.01.0 
AM 3500.08174.0   3.0
Alloy 3550.1215.54.5   N – 0.10
 Austenitic Precipitation Hardening Steels
17-10 P0.121710.0   P – 0.25
HNM Alloy0.03199.0   Mn – 3.5, P – 0.3
A 2860.051525.01.5 0.15Ti – 2.2, V – 0.3

Superalloys

Alloy X-750MatrixPrecipitateSolution annealing (°C)Aging (°C)
Inconel 718Ni-basisγ’ + γ”980–1050720 + 620
Alloy X-750Ni-basisγ’980–1050700–760
René 41Ni-basisγ’1050–1080760–815
WaspaloyNi-basisγ’1040–1065760–850

Various

AlloyMatrixPrecipitateSolution annealing  (°C)Aging (°C)
Ti-6Al-4VTitaniumα  β950–1000480–600
Cu-BeCopperBe-precipitates760–800315–350
Mulberry (U)U-MoU-Mo precipitates800–900350–500
precipation hardening

precipitation hardening for various industries

Precipitation hardening is applied in almost all industries. Critical factors are the metal to be used and the required mechanical properties for the application.

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precipation hardening process

frequently asked questions about precipitation hardening

Which materials are suitable for precipitation hardening?

Precipitation hardening is the main method to increase the strength of certain copper, titanium, and aluminum alloys. These alloys do not have the possibility of a polymorphic phase transformation and therefore cannot be hardened classically (as is possible for martensite).

What is a yield strength?

The yield strength describes the limit of elastic strain before it transitions into permanent plastic strain (deformation). This is determined with a uniaxial and uniform tensile test. For many materials, the yield strength cannot be clearly determined with a tensile test or is not clear. Therefore, the 0.2% yield strength is often used instead.

How long does the precipitation hardening process take?

The temperature determines the diffusion rate, the type of precipitate, and the rate of precipitation formation. Nucleation, the growth of the nuclei, and the final precipitation hardening can be controlled.

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